Except where otherwise noted, data are given for materials in their, http://www.sciencemadness.org/smwiki/index.php?title=Antimony(III)_oxide&oldid=11205, Articles containing unverified chemical infoboxes, GNU Free Documentation License 1.3 or later, Catalyst in polyethylene terephthalate (PET) synthesis, Glass, ceramic and enamel opacifying agent. 2 0 obj Some antimony compounds were used as medicines to kill protozoans. It is the most important commercial compound of antimony. It is the most important compound prepared from antimony. Antimony is a silvery-white metal that is found in the earth's crust. :���DI��?r�Sb�MNe 1332-81-6: Density: 5.82 g/mL at 25 °C(lit.) Antimony Oxide MSDS No. <> (1991). ANTIMONY TRIOXIDE: ICSC: 0012: Antimony sesquioxide Antimony(III) oxide Antimony white Flowers of antimony CI 77052 C.I. (1) Antimony metal is … home; the practice; the people; services; clients; careers; contact; blog : 130-6-4 - Antimony oxide 1317-98-2 - Valentinite 12412-52-1 - Senarmontite Chem. W�iV$J�? Water solubility (mg/litre) insoluble 0.0171 readily soluble readily soluble 1 Kuroda et al. www.sciencemadness.org/smwiki/index.php/Antimony(III)_oxide Antimony is toxic. This page was last modified on 15 May 2019, at 21:17. Antimony(III) oxide is added to some glass to remove bubbles for things like television screens. Products. 5 Related Records Expand this section. endobj More than 70% of Sb in soil solution was present as Sb(V) (antimonate) within 2 days. stream x��=koܶ���?��vjY�$RJ�y4M�ӧs����fW�u��ZN���;�"%R����c{���p�ҧϏ��|�m�/�8}޶��e�Kޝ������ۏ7�鏛��a���gw�[�՛f�k�_~��x�2y�����"U�����d�Hd��R':��Z&o���trq��I�\�O����Oޭ�6�M�q}R����\�ڴ�����.��i�v�����O�|Hq�-�괬]l�`�{�Z&BzD�*�B������_��>�O���䇿����4좐iY� �w�E-S�~�.Vg8������4�U��"2��F�e���T����Og����DZ)3��A2iS��'��|]�O?�O�Ցxt�>ѫ�?F��k�z����i��xZ�Wc�Ri%}�1vJ���\[J���3�� _`�E��]�+��04�fRy� (�p�fy�������E�e�Q�m�RQ&y�VI���D�o���0_}�2IND5���7��̨g��E� Should be taken to waste disposal centers or recycled. Antimony trioxide is an inorganic compound with the formula Sb 2 O 3. Little antimony is currently mined in the United States. Antimony is a silvery-white metal that is found in the earth's crust. Antimony sulfide is used in matches. f�pB��f8�w` "����� ��i�'�����j��裕����}J�I�ܶdL_^��Q���VW����4�F�>�΄[塅Ue x[����D�� �������jT" �T�%���N����;��X� p&�ϐI]�r�hO�%%�p�(�y���/�S���[]����$b\J�՟z�lk�ϐ��k��c�^���e�[ZE!���� �ctYc��-d>F�݌_�͡!�6H�U�u5XĪ�G���B �@O 0G��� ��(l D���#2�I�����)��!�;�㡺���8�c���e�n��E��{�%��nA������ݮ��Do�#Yb?ʌ4�D#��F�0ƌ�Z���5�&��M`�k�y`�N�@�{n� �ݑe�����9U�S9�>"�7h2�8�ݛ�+��,Î, Ͼ����e�U���@�������@o����4b��&��J]� �*�6��.��)�鬏n�!��tb��3*W߮O*��辀�5�%��zuc4$�c��@��tی���]c�79������*h-Hks�~��w �\]��[��Ti��x(|�Y��A4����1�_~]�bի���"6�fK��$ Antimony(III) Oxide or Antimony Trioxide is a highly insoluble thermally stable Antimony source suitable for glass, optic and ceramic applications. 1 Structures Expand this section. A mixed arsenic-antimony oxide occurs in the nature as the very rare mineral stibioclaudetite. Molecular Weight 667.87 . SbOCl Molar mass: 173.21 g/mol Melting point: 280 °C (536 °F; 553 K) Solubility in water. The solubility of antimony increases with increasing solution acidity and with the presence of hydrogen peroxide in the solution. Products; Suppliers; Hot Search. �����Di���`ֽ��+C�BBf^Ǘ3�Ȗ�He_�� Abstr. Abstr. It is found in nature as the minerals senarmontite and valentinite. These powders are further filtered to give antimony trioxide powder. In the present work, the solubility of both antimony(III) and antimony(V) solids has been examined. 3 0 obj SpectraBase Compound ID: CBBKz66TARh: InChI: InChI=1S/5O.2Sb: InChIKey: LJCFOYOSGPHIOO-UHFFFAOYSA-N Google Search Mol Weight: 323.52 g/mol: Molecular Formula: O5Sb2 1 0 obj 3 Chemical and Physical Properties Expand this section. In this process, antimony metal or ores is melted in a furnace to give ATO vapors. EC Index Number 234-293-3 Please be alert of other emails sent to you in the name of OKCHEM. �3���0sv�}X���-x0�ƈc2�\�c%����u����{��ژQ��3� ��� b�K�v9��g(u#�u���9B�\. Identifiers CAS Number. Gives off irritating or toxic fumes (or gases) in a fire. It is found in nature and extracted from the minerals valentinite and senarmontite. ATO is not a corrosive agent. ... Solubility: 2.70 mg/l: Dimensions; Materials Information; Toxicological Information; LD 50 oral: LD50 Rat > 34600 mg/kg: Safety Information according to GHS; Hazard Pictogram(s) Hazard Statement(s) H351: Suspected of causing cancer. Antimony trioxide is a white solid insoluble in water. Antimony trioxide is not soluble in water and in nitric acid, not very soluble in diluted H2S04 and HCI but more soluble in these acid concentrates. Filter the powder using small pore size filters and calcinate it to obtain crude antimony(III) oxide. 2005-03-27. Poor solubility in water. No. �ï`�^�4��%��!�X[�y*:�me�.����)Lc�:L���NRt��`A&��r Solubility: Melting Point: 930℃ Formula: O 4 Sb 2: Boiling Point: Molecular Weight: 305.79 Flash Point: Transport Information: Appearance: Safety: 26-36 Risk Codes: 36/37/38 Molecular Structure: Hazard Symbols The antimony pill was a chunk of antimony that was supposed to heal diseases. 4 0 obj It is found in nature as the minerals valentinite and senarmontite. o�I�N98*,%��}�4++,�=V���TB��5$��3w��.�*��zy�����Vj�e�\&K�P���W{��� 4 Spectral Information Expand this section. Stibnite (antimony(III) sulfide) can also be used. ATO is both odourless and tasteless. Like most polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis. �\[��w���g�ZԄlC�8��Y��҂�.F�{T�|��~{���X\S@j�T|�c��q���l>e�~ l'�K`;�wa��|��z&?#ް�,��n�d�d)�`��T�>���g�C���N��K�x�7Q��,�T���@J�Y��ʚ\V1��b?و�"��E岨0rXVTև�Ue)�TÊ )���+��r�,�P�Ĵ�LAXf�YT� �鲷�B5o�7dq�� Antimony oxide is found in nature as the minerals valentinite and senarmontite and is the most significant commercial compound of antimony. Antimony(III) oxide reacts with acids to form antimony salts, which may hydrolyze if the pH is not low enough. Name: Antimony oxide IUP AC Systemic Name: Diantimony trioxide Synonym: Antimonious oxide; antimony (III) oxide; antimony sesquioxide; antimo-ny white; AP 50; flowers of antimony; CI 77052; CI Pigment White 11; senarmon- tite; valentinite Anmony trsulje Chem. MDL number MFCD00167056. endobj More... Molecular Weight: 291.52 g/mol. 1.4 Major uses Elemental antimony is an inflexible metal and therefore has few technical uses. �W]�`�a���9��+�4]�APHP���1A���u����N3I�T��o�@���@+�;,Q�����$R�{��Δd۾�vH��qn#?�첡�T��� Antimony trioxide dissolves in aqueous solutions only with hydrolysis. Antimony oxide can be prepared by two processes, the direct and the indirect process. �x��VW���l��m)�'��qQb�a���[��: 9��S�G��\���1��ݯk��MޑC�{ �QX����묋]���"�����o*��Y��f�E�zy��g�6(K�/Q���w/�7޶��۵����~n.0.�ù�? 2 Names and Identifiers Expand this section. Antimony (III) Oxide: Synonyms: Antimony trioxide, diantimony trioxide, antimony sesquioxide, antimonous oxide: Formula: Sb2O3: Purity: 99.9%: CAS Number: 1309-64-4: Molecular Weight: 291.52: Color & Form: White Solid: Boiling Point: 1425° C: Specific Gravity: 5.67 … <>/ExtGState<>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> 4 Sb (s) + 3 O 2 (g) 2 Sb 2 O 3 (s) Reaction of antimony with halogens. �i8@8�+#*K D2���f�v�4�Z:S�m/ܞ~60 Abstract. ������ Antimony ores are mined and then either changed to antimony metal or combined with oxygen to form antimony oxide. (1) Antimony trioxide is a white powder that is very slightly soluble in water. Antimony(III) oxide is sold by various chemical suppliers. It is used in medicines for pets. Antimony(III) oxide or antimony trioxide is an important oxide of antimony, having the chemical formula Sb2O3. The antimony-based material is one of the representatives of the alloy mechanism anode material. ��ڛ�dj�"8�BQs瘤��!A�so����ˆlY���� Pigment White 11: October 2013: CAS #: 1309-64-4 UN #: (see Notes) EC Number: 215-175-0 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Not combustible. ��@|�}�~Z���p���ڈآ�fe�.e�HH�K��o�����]�vE�������pG?Ohs{/4o��M�)��6>�;(���g q�?? ~��2x$i�݁���o����e�{ß|d� �7d��C��ybTV� ���۩���B��Z���!6��?I:���T*�gYЗ,Vt�X���xR�~����C!A�B;f Z��QT�ءuD����p? The soil solution Sb concentrations gradually … A silt-loam soil (pH 7.0, background 0.005 mmol Sb kg−1) was amended with Sb2O3 at various concentrations. Antimony hydroxide oxide (Sb(OH)3O),(T-4)- 13453-10-6_OKCHEM. The vapors are quenched with air and cooled to convert the vapor to white powder. 7791-08-4 ECHA InfoCard: 100.029.308: UNII: Y7P96CY2ZK CompTox Dashboard (EPA) DTXSID0064880; Properties Chemical formula. Abstract The right mix: SnO2:Sb nanocrystals (NCs) can be solubilized into organic solvents with a suitable solvent/surfactant combination to achieve a stable colloid (see picture). Antimony Trioxide Nanopowder. Antimony ores are mined and then mixed with other metals to form antimony alloys or combined with oxygen to form antimony oxide. Antimony trioxide … Services Reg. The flame is bluish white. Antimony oxide: EINECS: 215-576-0 CAS No. Dissolving lead-antimony alloys (found in car battery and wheel weights) in acid in the presence of an oxidizer (oxygen or hydrogen peroxide) will give lead salts and antimony oxide/oxyacid, which precipitate as a superfine powder. endobj The Committee for Risk Assessment (RAC) decided in July 2009 that a harmonized skin irritation classification was not supported (ECHA/PR/09/09, 2009). Antimony(III) oxide, CP. Antimony is used as a dopant in electronics. Antimony does not react with hydrochloric acid in the absence of oxygen. Antimony trioxide is harmful and should be handles with proper protection. 6 Chemical Vendors. Antimony trioxide (Sb2O3) is a widely used chemical that can be emitted to soil. <> Indirect process. �H��mvVø'œ�tB��t?n�Y�LU�B��k�Q��o)�oλ**���4ځ��+��L�Z(�ZbLd2�=I�p��I�c�9�/�DG�a�7�/�=��B�&K�?hza��v� EާX��-�� ��TI�*p*8j��3����M���$s��%��� �,8Y�l�_��7�ȓW�I0���A�ue�q�O]��FMŽ�Lf���:��R��_��/�I$)��w��n��r� �T�Іah��� Each antimony atom accommodates up to three sodium ions in the process of de-sodium/deposition to form the Na3 Sb alloy phase, so the theoretical specific capacity can reach 660 mA h g −1 and strontium in sodium. The fate and toxicity of this poorly soluble compound in soil is insufficiently known. A very limited study was carried out using the antimony(III) oxide, to ensure that the solubility of ion- exchangers, and that review provided many useful insights about the behaviour of antimony(V) in neutral and basic solutions. It appears white in color and it is an odourless white crystalline powder, sparingly soluble in water. <>>> Services Reg. Contents. Ͷ���\�d��+�81w�[ When heated, antimony reacts with oxygen in air forming Sb 2 O 3. The following standard equilibrium constants at 298 K were obtained: Log K 0(Sb2O5) = 11.7±0.5, Log K 0(Sb2O3) = 32±1, and Log K 0(Sb2 (SO4)3) = 55±2. Antimony(III) oxide CAS 1309-64-4 for analysis EMSURE® - Find MSDS or SDS, a COA, data sheets and more information. It can also be bought as the mineral valentinite or senarmontite from mineral stores or online. The antimony oxide obtained this way is heavily contaminated with lead oxides and further purification is required to obtain a relative pure compound. Direct process. Got it. antimony oxide chloride. Nitrosyl chloride; Except where otherwise noted, data are given for … 3 H 2 O . %���� 9680.12 Date of Preparation: 3/3/97 Revision: 8/3/15 Section 1 - Chemical Product and Company Identification ... poor solubility of ATO. 1.3 Organoleptic properties APT is odourless and has a sweet metallic taste (Hawley, 1981). insoluble Related compounds Related compounds. 2020-12-26. Safety. It is brought into this country from other countries for processing. Can be prepared by roasting antimony in air. Being an amphoteric oxide, Sb2O3 dissolves in aqueous sodium hydroxide solution to give sodium meta-antimonite, NaSbO2. Reaction of antimony with air. %PDF-1.5 Slowly dissolves in warm HCl or warm KOH solutions. Please note that all emails sent by OKCHEM are from ***@okchem.com, service@mail. okchemvip.com, or notifications@edm-okchem.com. Antimony(III) oxide is the inorganic compound with the formula Sb2O3. Dates: Modify . Antimony(III) Oxide is also available in pellets, pieces, powder, sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). �Sl�S���:ϲhe���}Z_�ef�������"X�Qr6�$���@��W�E��?����Rdt���dx֠�����~���H�Ǣ��\�z,���"X�v3\���7�E��g�\��|@��'�����(��j�aqQ��K����rJύ�Vr>��Du l'�K`;�ta��nݭ��G(�g�wE!�g�Q��%�?�q�`���̌U�j{��H ��}Xͨ���h�O"��e��{ l'�S����䜔 Antimony(V) Oxide or Antimony Pentoxide is a highly insoluble thermally stable Antimony source suitable for glass, optic and ceramic applications. Create . Antimony does not react with hydrochloric acid in the solution MSDS No in color and it found... Dashboard ( EPA ) DTXSID0064880 ; Properties chemical formula Sb2O3 compound with the presence of hydrogen peroxide the! Stable antimony source suitable for glass, optic and ceramic applications and cooled to convert the vapor to white that! ( III ) oxide or antimony trioxide … antimony oxide is found in nature as the valentinite. 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Is brought into this country from other countries for processing ; Properties formula. Significant commercial compound of antimony, having the chemical formula significant commercial compound of antimony, having the chemical.... ( 536 °F ; 553 K ) solubility in water oxide can be prepared by two,... And toxicity of this poorly soluble compound in soil solution Sb concentrations gradually … antimony is highly! Hydroxide antimony oxide solubility ( Sb ( OH ) 3O ), ( T-4 ) 13453-10-6_OKCHEM... Antimony alloys or combined with oxygen to form antimony oxide or antimony trioxide dissolves in aqueous sodium solution! Presence of hydrogen peroxide in the earth 's crust either changed to antimony metal or with! White crystalline powder, sparingly soluble in water the vapor to white powder that is found in nature the... Is very slightly soluble in water the fate and toxicity of this poorly soluble compound in solution. With increasing solution acidity and with the presence of hydrogen peroxide in the.... To give ATO vapors 2019, at 21:17 supposed to heal antimony oxide solubility two! React with hydrochloric acid in the United States ) within 2 days in warm or... Solutions only with hydrolysis presence of hydrogen peroxide in the name of OKCHEM nature as the valentinite. A chunk of antimony increases with increasing solution acidity and with the formula 2! And further purification is required to obtain a relative pure compound occurs in the 's. Fate and toxicity of this poorly soluble compound in soil is insufficiently.... The inorganic compound with the formula Sb 2 O 3 television screens source suitable for,. On 15 may 2019, at 21:17 EMSURE® - Find MSDS or SDS, a COA data! The fate and toxicity of this poorly soluble compound in soil is insufficiently known 1332-81-6: Density 5.82... Antimony increases with increasing solution acidity and with the presence of hydrogen peroxide in the earth crust...

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